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Piper kelleyi is a wild relative of black pepper that grows in Ecuador and Peru. The species is named in honor of American botanist Walter Almond Kelley and is a member of the Macrostachys clade of the pepper genus. Piper kelleyi features long, white, pendulous inflorescences and large leaves. It is mostly restricted to montane elevations and produces secondary compounds that deter most herbivores. The most important secondary compounds discovered from P. kelleyi are a prenylated benzoic acid and 2 chromanes that are unique to this species.