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Turbo-Hauser bases

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Turbo-Hauser bases are amido magnesium halides that contain stoichiometric amounts of LiCl. These mixed Mg/Li amides of the type R2NMgCl⋅LiCl are used in organic chemistry as non-nucleophilic bases for metalation reactions of aromatic and heteroaromatic substrates. Compared to their LiCl free ancestors Turbo-Hauser bases show an enhanced kinetic basicity, excellent regioselectivity, high functional group tolerance and a better solubility.
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    • Preparation 

    • Structure 

    • Reactivity